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KMID : 0043320110340091437
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Archives of Pharmacal Research
2011 Volume.34 No. 9 p.1437 ~ p.1442
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A versatile synthetic approach to grandisol monoterpene pheromone
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Han Young-Taek
Kim Nam-Jung
Jung Jong-Wha
Yun Hwa-Young
Lee Su-Jin
Suh Young-Ger
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Abstract
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A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.
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KEYWORD
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Synthesis, Grandisol, Pheromone, Palladium, Pesticide
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